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C4: Generators

L. A. Konopko1,2, A. A. Nikolaeva1,2 and T. E. Huber3
1Institute of Electronic Engineering and Nanotechnologies, Chisinau, Moldova, 2Int. Lab. of High Magnetic Fields and Low Temperatures, Wroclaw, Poland, 3Howard University, Washington, USA

In the thermoelectric-anisotropic media there is transverse to the temperature gradient electric field. At room temperature we have investigated the transverse thermopower in thin single-crystal Bi and Bi-Sn microwires for the purpose of using them in anisotropic thermoelectric generator. The single-crystal microwires in the diameter range 2 - 15 μm were prepared by the high frequency liquid phase casting in a glass capillary using an improved Ulitovsky technique; they were cylindrical single-crystals with (1011) orientation along the wire axis. In this orientation, the wire axis makes an angle of 19.5o with the bisector axis C1 in the bisector-trigonal plane. It was found that in temperature range of 200 – 300 K doping of bismuth wires with tin increases the thermopower anisotropy in comparison with Bi by a factor of 2 – 3. The experimental model of the anisotropic thermoelectric generator (ATG) was created from long Bi-0.05at%Sn microwire in a glass coating (long microwire was coiled into a flat spiral so that at any point of the spiral axis C3 and microwire axis lying in a plane perpendicular to the flat spiral). For the single crystal microwire with a core diameter d = 2 µm, outer diameter D= 20 µm and a length of 8 m ATG can generate voltage U=1 V at a transverse temperature gradient (perpendicular to the flat spiral) of 5 K.