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A6: Characterization
Novel thermoelectric materials especially for medium and high temperature application are in the focus for waste heat recovering systems not only in automotive applications. Beside the accurate determination of all thermoelectric properties and thereby the ZT-value, a detailed understanding of the processes inside the materials is needed. Hall-measurements are the well-known tool to investigate carrier concentration and mobility within metals, semiconductors and of course thermoelectric materials. Up to now, most commercial setups are only suitable for temperatures up to 400°C. The full characterization of high temperature materials like Oxides or Silicides require measurement temperatures of 600°C and above. Therefore Fraunhofer IPM developed a high temperature Hall-measurement-setup which allows measurements in this range. We will present first high temperature measurements on different materials and sample geometries performed with our new IPM-HT-Hall setup.